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From Tekran Inc., a world leader in the manufacture of
mercury detection instruments http://www.tekran.com/special/method.html.
Tekran manufactures a full line of analytical
instrumentation for the measurement of ultra-trace amounts
of mercury. Applications include ambient air,
water, biota, and other environmental samples.
Methodology: HALITOSIS
Program
Hg Approximate Levels
In Teeth Or Sputum
Informational Screening (HALITOSIS)
program
Although the "Hg Approximate Levels In Teeth Or
Sputum Informational Screening" program is meant only
for amusement, HALITOSIS provides a quick, screening
method for peoples' exhaled mercury levels.
Apparatus:
 | Model 2537A Mercury Vapor Analyzer
 | Short 1/4" TeflonŽ sampling line
 | Supply of small straws. (Usually purloined from the
nearest bar)
 | Drinking glass to hold supply of straws. (Source as
above) |
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Method:
1) The analyzer is set to sample continuously at 5 minute
cycles. A 2.5 minute cycle time would offer higher
throughput, but that would defeat the whole point of
wanting to pass the time.) The flow rate of the analyzer
is set to 1.5 litre/min.
2) At the start of a measurement cycle, a willing
participant is given a straw and given instructions on how
to blow into the analyzer. The straw is placed into the
end of the sample line. Since the straw is not a tight
fit, any excess exhalation flow is vented and any
shortfall in the exhalation rate are made up with ambient
air.
The instructions generally consist of something like:
"Take a deep breath. Exhale slowly and
steadily though the straw. Keep blowing until you run
out of breath. There is no need to cough up a lung or
anything, just take your time. Please don't
pass out. There is no prize for the highest (or lowest)
reading."
3) During the remainder of the sampling cycle, the
analyzer will sample ambient room air. This is a good time
to record the person's name and affiliation and the time
of the sample. It takes about 2 minutes after the end of
the sampling period for the result to become available.
The next person may be sampled during this period, since
the dual cartridge design of the Model 2537A allows
continuous sampling with overlapped analysis.
4) It's generally a good idea to record the ambient
levels before and after a series of tests to get some idea
of the background. The reported readings are not corrected
for background.
Observations and Comments
1) The method does not control for the rate of exhalation,
the exhalation time, or the total exhaled sample volume.
The actual concentrations in breath are likely to be far
higher than reported using this method since the majority
of time is spent sampling background air.
2) The method does not enforce standard conditions
prior to sampling. It is well known that the mechanical
action of chewing, or the chemical and thermal effects of
drinking hot beverages (particularly coffee) will liberate
relatively large amounts of mercury from fillings. The
only limits imposed by this method is that we don't allow
half eaten pizza to be fed into our inlet line since we
have found that it clogs the filters.
One must not lose sight of the
fact that the potential health effects of mercury amalgam
fillings is a serious issue. Our Links
page has one or two web sites dealing with this topic.
The Model 2537A clearly demonstrates that people with
mercury amalgam fillings can, under certain circumstances,
excrete relatively large concentrations of elemental
mercury in their breath. With appropriate front end
apparatus, the Model 2537A could easily yield quantitative
data. The 2.5 minute cycle time allows relatively high
sample throughput and provides ample sensitivity for any
measurement that could be contemplated.
For a sampling of results from actual breath
measurements, check out the events listed at the end of
our What's
New page.

Scientific Conferences and Trade Shows
Tekran exhibits at a number of scientific conferences
and trade shows each year. The listings below will let you
know where we have been and where we plan on exhibiting.
What goes on at these Gala Events?
We try to have at least one of our Model 2537A monitors
running during the show, measuring ambient air levels at
the conference. As a general rule, we find that mercury
levels in the room track the number of people present. In
a small room, we find that levels go up after coffee has
been served. This is consistent with speculation that the
Model 2537A is actually monitoring emissions from
attendees' dental amalgam fillings.
Those of you who have attended or exhibited at trade
shows will know that things can occasionally get somewhat
slow, boring, tedious, monotonous, wearisome, and dull. To
pass the time, we started allowing other exhibitors to
blow into our instrument. This became an immediate hit,
since it made time pass more quickly for the other
exhibitors too. Before we knew it, everyone wanted to blow
into our box.
We quickly found that this concealed all of the subtle
background variations we had been recording. Our
beautiful, multi-colored graph automatically scales itself
to the highest reading found, and these mouth readings
were sometimes hundreds of times higher than the
backgrounds we had been measuring. The subtle ambient
fluctuations were reduced to a flat line hugging the X
axis.
Thus started our Hg Approximate Levels
In Teeth Or Sputum Informational
Screening (HALITOSIS) program.
We are the first to admit that HALITOSIS is not
quantitative. We make no claim as to the health effects
(or lack thereof) of any readings we have found. We do not
want to hear from lawyers representing any dental
associations anywhere.

We occasionally keep a record of the individuals and
the mercury levels we measured when they blew into our
analyzer. We have done this for quite a few shows, but in
most cases, we misplaced the napkins that we were using as
our official recording medium. We have become more
organized now, and will be making the results available
here. So, if you have had HALITOSIS, the whole world will
now know.
We occasionally keep a record of the individuals and
the mercury levels we measured when they blew into our
analyzer. We have done this for quite a few shows, but in
most cases, we misplaced the napkins that we were using as
our official recording medium. We have become more
organized now, and will be making the results available
here. So, if you have had HALITOSIS, the whole world will
now know.
We would like to thank all those who took the time
to be tested and allowed us to include their results in
the tables below!
 | AWMA
Deposition to the Great Waters (Oct 26-28, 1996)
 | Pittcon'97
March 17 - 20, 1997
 | AWMA
Measurement of Toxic and Related Air Pollutants April
29 - 30, 1997
 | AWMA
Main Meeting and Exhibition, Toronto, June 10 - 12,
1997
 | AWMA
Main Meeting and Exhibition, San Diego, June 14-17,
1998
 | Mercury
in the Northeast States and Eastern Canada Conference,
Fredericton, New Brunswick, September 21 - 23, 1998
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